Thermal annealing effect on poly(3-hexylthiophene): fullerene:copper-phthalocyanine ternary photoactive layer.
Identifieur interne : 000322 ( Main/Exploration ); précédent : 000321; suivant : 000323Thermal annealing effect on poly(3-hexylthiophene): fullerene:copper-phthalocyanine ternary photoactive layer.
Auteurs : RBID : pubmed:23766722English descriptors
- KwdEn :
- Copper (chemistry), Copper (radiation effects), Electric Power Supplies, Equipment Design, Equipment Failure Analysis, Fullerenes (chemistry), Fullerenes (radiation effects), Hardness, Hot Temperature, Indoles (chemistry), Indoles (radiation effects), Light, Materials Testing, Membranes, Artificial, Organoselenium Compounds (chemistry), Organoselenium Compounds (radiation effects), Solar Energy.
- MESH :
- chemical , chemistry : Copper, Fullerenes, Indoles, Organoselenium Compounds.
- chemical , radiation effects : Copper, Fullerenes, Indoles, Organoselenium Compounds.
- Electric Power Supplies, Equipment Design, Equipment Failure Analysis, Hardness, Hot Temperature, Light, Materials Testing, Membranes, Artificial, Solar Energy.
Abstract
We have fabricated poly(3-hexylthiophene) (P3HT)/copper phthalocyanine (CuPc)/fullerene (C60) ternary blend films. This photoactive layer is sandwiched between an indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT/PSS) photoanode and a bathocuproine (BCP)/aluminium photocathode. The thin films have been characterized by atomic force microscope (AFM) and ultraviolet/visible spectroscopy in order to study the influence of P3HT doping on the morphological and optical properties of the photoactive layer. We have also compared the I-V characteristics of three different organic solar cells: ITO/PEDOT:PSS/CuPc₀.₅:C60₀.₅/BCP/Al and ITO/PEDOT:PSS/P3HT₀.₃:CuPc₀.₃:C60₀.₄/BCP/Al with and without annealing. Both structures show good photovoltaic behaviour. Indeed, the incorporation of P3HT into CuPc:C60 thin film improves all the photovoltaic characteristics. We have also seen that thermal annealing significantly improves the optical absorption ability and stabilizes the organic solar cells making it more robust to chemical degradation.
DOI: 10.1155/2013/914981
PubMed: 23766722
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Thermal annealing effect on poly(3-hexylthiophene): fullerene:copper-phthalocyanine ternary photoactive layer.</title><author><name sortKey="Derouiche, H" uniqKey="Derouiche H">H Derouiche</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire de Photovoltaïques, Centre de Recherches et des Technologies de l'Energie, BP 95, 2050 Hammam-Lif, Tunisia. hderouiche@yahoo.fr</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Photovoltaïques, Centre de Recherches et des Technologies de l'Energie, BP 95, 2050 Hammam-Lif</wicri:regionArea></affiliation></author><author><name sortKey="Mohamed, A B" uniqKey="Mohamed A">A B Mohamed</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1155/2013/914981</idno><idno type="RBID">pubmed:23766722</idno><idno type="pmid">23766722</idno><idno type="wicri:Area/Main/Corpus">000578</idno><idno type="wicri:Area/Main/Curation">000578</idno><idno type="wicri:Area/Main/Exploration">000322</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Copper (chemistry)</term><term>Copper (radiation effects)</term><term>Electric Power Supplies</term><term>Equipment Design</term><term>Equipment Failure Analysis</term><term>Fullerenes (chemistry)</term><term>Fullerenes (radiation effects)</term><term>Hardness</term><term>Hot Temperature</term><term>Indoles (chemistry)</term><term>Indoles (radiation effects)</term><term>Light</term><term>Materials Testing</term><term>Membranes, Artificial</term><term>Organoselenium Compounds (chemistry)</term><term>Organoselenium Compounds (radiation effects)</term><term>Solar Energy</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Copper</term><term>Fullerenes</term><term>Indoles</term><term>Organoselenium Compounds</term></keywords><keywords scheme="MESH" type="chemical" qualifier="radiation effects" xml:lang="en"><term>Copper</term><term>Fullerenes</term><term>Indoles</term><term>Organoselenium Compounds</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Electric Power Supplies</term><term>Equipment Design</term><term>Equipment Failure Analysis</term><term>Hardness</term><term>Hot Temperature</term><term>Light</term><term>Materials Testing</term><term>Membranes, Artificial</term><term>Solar Energy</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">We have fabricated poly(3-hexylthiophene) (P3HT)/copper phthalocyanine (CuPc)/fullerene (C60) ternary blend films. This photoactive layer is sandwiched between an indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT/PSS) photoanode and a bathocuproine (BCP)/aluminium photocathode. The thin films have been characterized by atomic force microscope (AFM) and ultraviolet/visible spectroscopy in order to study the influence of P3HT doping on the morphological and optical properties of the photoactive layer. We have also compared the I-V characteristics of three different organic solar cells: ITO/PEDOT:PSS/CuPc₀.₅:C60₀.₅/BCP/Al and ITO/PEDOT:PSS/P3HT₀.₃:CuPc₀.₃:C60₀.₄/BCP/Al with and without annealing. Both structures show good photovoltaic behaviour. Indeed, the incorporation of P3HT into CuPc:C60 thin film improves all the photovoltaic characteristics. We have also seen that thermal annealing significantly improves the optical absorption ability and stabilizes the organic solar cells making it more robust to chemical degradation.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">23766722</PMID><DateCreated><Year>2013</Year><Month>06</Month><Day>14</Day></DateCreated><DateCompleted><Year>2013</Year><Month>09</Month><Day>30</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Electronic-Print"><Journal><ISSN IssnType="Electronic">1537-744X</ISSN><JournalIssue CitedMedium="Internet"><Volume>2013</Volume><PubDate><Year>2013</Year></PubDate></JournalIssue><Title>TheScientificWorldJournal</Title><ISOAbbreviation>ScientificWorldJournal</ISOAbbreviation></Journal><ArticleTitle>Thermal annealing effect on poly(3-hexylthiophene): fullerene:copper-phthalocyanine ternary photoactive layer.</ArticleTitle><Pagination><MedlinePgn>914981</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1155/2013/914981</ELocationID><Abstract><AbstractText>We have fabricated poly(3-hexylthiophene) (P3HT)/copper phthalocyanine (CuPc)/fullerene (C60) ternary blend films. This photoactive layer is sandwiched between an indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT/PSS) photoanode and a bathocuproine (BCP)/aluminium photocathode. The thin films have been characterized by atomic force microscope (AFM) and ultraviolet/visible spectroscopy in order to study the influence of P3HT doping on the morphological and optical properties of the photoactive layer. We have also compared the I-V characteristics of three different organic solar cells: ITO/PEDOT:PSS/CuPc₀.₅:C60₀.₅/BCP/Al and ITO/PEDOT:PSS/P3HT₀.₃:CuPc₀.₃:C60₀.₄/BCP/Al with and without annealing. Both structures show good photovoltaic behaviour. Indeed, the incorporation of P3HT into CuPc:C60 thin film improves all the photovoltaic characteristics. We have also seen that thermal annealing significantly improves the optical absorption ability and stabilizes the organic solar cells making it more robust to chemical degradation.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Derouiche</LastName><ForeName>H</ForeName><Initials>H</Initials><Affiliation>Laboratoire de Photovoltaïques, Centre de Recherches et des Technologies de l'Energie, BP 95, 2050 Hammam-Lif, Tunisia. hderouiche@yahoo.fr</Affiliation></Author><Author ValidYN="Y"><LastName>Mohamed</LastName><ForeName>A B</ForeName><Initials>AB</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2013</Year><Month>05</Month><Day>20</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>ScientificWorldJournal</MedlineTA><NlmUniqueID>101131163</NlmUniqueID><ISSNLinking>1537-744X</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Fullerenes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Indoles</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Membranes, Artificial</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Organoselenium Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>poly(3-hexyl)selenophene</NameOfSubstance></Chemical><Chemical><RegistryNumber>574-93-6</RegistryNumber><NameOfSubstance>phthalocyanine</NameOfSubstance></Chemical><Chemical><RegistryNumber>789U1901C5</RegistryNumber><NameOfSubstance>Copper</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Langmuir. 2007 Jan 16;23(2):834-42</RefSource><PMID Version="1">17209641</PMID></CommentsCorrections></CommentsCorrectionsList><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Copper</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">radiation effects</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Electric Power Supplies</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Equipment Design</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Equipment Failure Analysis</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Fullerenes</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">radiation effects</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Hardness</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Hot Temperature</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Indoles</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">radiation effects</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Light</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Materials Testing</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Membranes, Artificial</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Organoselenium Compounds</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">radiation effects</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Solar Energy</DescriptorName></MeshHeading></MeshHeadingList><OtherID Source="NLM">PMC3673347</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="ppublish"><Year>2013</Year><Month></Month><Day></Day></PubMedPubDate><PubMedPubDate PubStatus="received"><Year>2013</Year><Month>4</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2013</Year><Month>5</Month><Day>8</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2013</Year><Month>5</Month><Day>20</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>6</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>6</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>10</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1155/2013/914981</ArticleId><ArticleId IdType="pubmed">23766722</ArticleId><ArticleId IdType="pmc">PMC3673347</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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